(2E)-3-(3,4-Dimeth­oxy­phen­yl)-1-(4-hy­droxy­phen­yl)prop-2-en-1-one

نویسندگان

  • Jerry P. Jasinski
  • Ray J. Butcher
  • V. Musthafa Khaleel
  • B. K. Sarojini
  • B. Narayana
چکیده

In the title compound, C(17)H(16)O(4), the dihedral angle between the mean planes of the hy-droxy-phenyl and dimeth-oxy-phenyl rings is 19.34 (7)°. The mean plane of the prop-2-en-1-one group, the active site in this mol-ecule, makes angles of 7.40 (8) and 13.25 (8)°, respectively, with the hy-droxy-phenyl and dimeth-oxy-phenyl rings. The crystal packing is stabilized by O-H⋯O hydrogen bonds, weak inter-molecular C-H⋯O and π-π stacking inter-actions [centroid-centroid distance = 3.7386 (9) Å].

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منابع مشابه

(E)-3-(3,4-Dimeth­oxy­phen­yl)-1-(2-hy­droxy­phen­yl)prop-2-en-1-one

In the title compound, C(17)H(16)O(4), the dihedral angle between the mean planes of the hy-droxy-phenyl and dimeth-oxy-phenyl rings is 5.9 (6)°. The mean plane of the prop-2-en-1-one group makes dihedral angles of 3.6 (0) and 2.6 (7)° with the hy-droxy-phenyl and dimeth-oxy-phenyl rings, respectively. An intra-molecular O-H⋯O hydrogen bond occurs. The crystal packing is stabilized by weak inte...

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The mol-ecular structure of the title compound, C(17)H(15)BrO(3), consists of a bromo-phenyl and a 3,4-dimeth-oxy-phenyl group linked through a prop-2-en-1-one spacer. The C=C double bond displays an E conformation, while the carbonyl group shows an S-cis conformation relative to the double bond.

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Crystal structures of (2E)-1-(3-bromo­thio­phen-2-yl)-3-(2-meth­oxy­phen­yl)prop-2-en-1-one and (2E)-1-(3-bromo­thio­phen-2-yl)-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one

In the mol-ecules of the title compounds, (2E)-1-(3-bromo-thio-phen-2-yl)-3-(2-meth-oxy-phen-yl)prop-2-en-1-one, C14H11BrO2S, (I), which crystallizes in the space group P-1 with four independent mol-ecules in the asymmetric unit (Z' = 8), and (2E)-1-(3-bromo-thio-phen-2-yl)-3-(3,4-di-meth-oxy-phen-yl)prop-2-en-1-one, C15H13BrO3S, (II), which crystallizes with Z' = 8 in the space group I2/a, the...

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011